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Extra resources for Bretherick's Handbook of Reactive Chemical Hazards 2 vols set
Silver fluoride [7775-41-9] AgF Ag + F Calcium hydride See Calcium hydride: Silver halides Non-metals Mellor, 1941, Vol. 3, 389 Boron reacts explosively when ground with silver fluoride; silicon reacts violently. Titanium Mellor, 1941, Vol. 7, 20 Interaction at 320 C is incandescent. See other METAL HALIDES, SILVER COMPOUNDS 0014. Silver difluoride [7783-95-1] AgF2 2+ F Ag F Boron, Water Tulis, A. J. , Proc. 7th Symp. Explos. Pyrotechnics, 1971, 3(4), 1—12 Mixtures of boron and silver difluoride function as detonators when contacted with water.
This is known to catalyse polymerisation of trichloroethylene, producing more hydrogen chloride and heat. The reaction is self-accelerating and can develop a temperature of 1350 C . Trichloroethylene cleaning baths must be kept neutral with sodium carbonate, and free of aluminium dust. Halocarbon solvents now available with added stabilisers (probably amines) show a reduced tendency to react with aluminium powder . Aluminium powder undergoes an exothermic and uncontrollable reaction with dichloromethane above 95 C under appropriate pressure .
Chem. , 1955, 1255 3. Kabanov, A. A. , Russ. Chem. , 1975, 44, 538 4. Ryabykh, S. M. , Chem. 86 kJ/g). While pure silver azide explodes at 340 C , the presence of impurities may cause explosion at 270 C. It is also impact-sensitive and explosions are usually violent . Its use as a detonator has been proposed. Application of an electric field to crystals of the azide will detonate them, at down to —100 C , and it may be initiated by irradiation with electron pulses of nanosecond duration .